It's probably because of some pesky firewall. You have administrator access, don't you? You could just disable it.
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Ahhh I gave in and got it again. I played it years ago, and thought I lost the addiction but it got to me again. Going to start again today. Possibly an Amazon with max out on multiple shot.
EDIT: Ok it says: This problem was caused by a compatibility issue between Windows Vista and this version of Diablo II. This program was created by Blizzard.
It won't allow it to run on Windows Vista. Any way to get around it?