I was gonna mention the "Eyes On Me" scene, but I figured that would be really cliche and "done to death" for lack of better wording.
Although, that did make me think of when Squall saves Rinoa from the sorceress capsule thing at the teardrop spider whatever place. That's a good scene.
Also Fuujin's speech. When she thinks to herself (I guess) but there's a bunch of words besides "RAGE!" and "DIE!"
Final Fantasy IX: When Garnet flies off of the tower on the rope.
FFVII: When Cait Sith jumps into the Temple of the Ancients in order for the group to get the black materia. And when Cid saves Shera. <3
I'm really really anti-XIII, but the scene with Sazh and Vanille when she says she's the reason Dajh is a crystal was okay.