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Luxord was a gentleman, per usual. He's the only one who I think was decent throughout.
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Marluxia, even if he was interested in Roxas's Keyblade, appeared to be well-mannered and was, well, nice.
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Lexaeus. Ignoring the, uh, bitchslap, which was only for the Limit Break, he was also well-mannered. A bit tough, but harmless.
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Demyx. Also ignoring the many times he ditched Roxas and let him do all the work, he was civil and nice to him.
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Xigbar. He and Demyx kind of tie. Despite annoying the hell out of Roxas sometimes, he seemed pretty good.
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Zexion. He wasn't that bad. Just his nose was too high in the air. Bu the took time to explain things to Roxas, asked him for any questions, and seemed to be patient.
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Larxene. In the beginning, yes, she was insulting and the bitch. But near the end, she started to somewhat warm up to him. Gave him a Potion, gave a half compliment. Hell, people, I think this is the first time we've ever seen
Larxene do this to anyone. Unfortunately, any more progress on that was hindered due to the events after.
Vexen was too belittling. It felt like he thought Roxas was below him sometimes, and wouldn't be able to stand around him unless ordered to. He was even a bigger bitch, actually. I was happy when Roxas talked back to him when he was turning around instead of just standing there. Saïx was an ass. But an awesome ass anyway

. Xaldin was...Xaldin. And Xemnas...
*sees the scene where Roxas looks up at him in the throne room when he first joined*
Creepy pedo smile.
Nuff' said.